Moves Originating from TCG

Gen VI(Pre-introduction):

Freeze-Dry: Articuno (Fossil 2), Latios (Nintendo Promo 15), Pryce's TM 02 (VS 116)
Infestation: Sabrina's Gastly (Gym Heroes 93), Tangela (EX Legend Maker 44), Tentacool (Triumphant 80), Muk (Next Destinies 53), Omastar (Skyridge 23), Dratini (Triumphant 62), Garbodor (Noble Victories 49), Milotic ex (EX Emerald 96)*
Noble Roar: Monferno (Plasma Storm 16), Entei (Neo Revelation 6)

Gen V(Pre-introduction):
Dual Chop: Meditite (EX Hidden Legends 65), Riolu (Unleashed 60), Corphish (EX Deoxys 57), Machop (Expedition 117)
Heal Pulse: Dragonair (EX Dragon 14)
Soak: Blastoise (Secret Wonders 2)

*Infestation/まとわりつく is also present in Gloom's Japanese Gold Dex entry.

Gen IV:
Ice Shard: Misty's Dewgong (Gym Challenge 54), Walrein ex (EX Legend Maker 89)

Gen III:
Grudge: Haunter (Vending S3 1)

Gen II(Pre-introduction):
Whirlpool: Poliwrath (Base Set 13), Dark Vaporeon (Team Rocket 45)*
Conversion 2: Porygon (Base Set 39), Porygon (Team Rocket 48), Porygon (Vending S1)
Destiny Bond: Gastly (Base Set 50)
Nightmare: Drowzee (Team Rocket 54), Haunter (Fossil 6) , Sabrina's Haunter (Gym Challenge 55)

*Whirlpool/うずしお  is also present in Vaporeon's Japanese dex entry from Vaporeon (Jungle 12).